Journal of Dentistry
Volume 34, Issue 8 , Pages 525-532 , September 2006

Characterisation of fluorine containing glasses by 19F, 27Al, 29Si and 31P MAS-NMR spectroscopy

  • R.G. Hill

      Affiliations

    • Imperial College of Science, Technology and Medicine, Department of Materials, Prince Consort Road, London SW7 2BP, UK
    • Corresponding Author InformationCorresponding author.
  • ,
  • A. Stamboulis

      Affiliations

    • Metallurgy and Materials, University of Birmingham, Edgbaston, Birmingham B15 2TT, UK
  • ,
  • R.V. Law

      Affiliations

    • Imperial College of Science, Technology and Medicine, Department of Chemistry, Exhibition Road, SW7 2AY, UK

Received 27 July 2005 ,Accepted 27 August 2005.

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  2. Hill RG, Wilson AD. Some structural aspects of glasses used in ionomer cements. Glass Technology. 1988;29:150–157
  3. Griffin S, Hill RG. Influence of glass composition on the properties of glass polyalkenoate cements. Part I. Influence of aluminium to silicon ratio. Biomaterials. 1999;20:1579–1586
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  6. Zeng Q, Stebbins JF. Fluoride sites in aluminosilicate glasses. High resolution 19F NMR results. 2000;85:863–886
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  8. Stebbins JF, Zeng Q. Cation ordering at fluoride sites in silicate glasses: a high-resolution 19F NMR study. Journal of Non Crystalline Solids. 2000;262:1–5
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  10. Hill R, Stamboulis A, Law RV. Characterisation of the structure of calcium alumino-silicate and calcium fluoro-alumino-silicate. Glasses by Magic Angle Nuclear Magnetic Resonance (MAS-NMR). 2004;333:101–107
  11. Rafferty A, Clifford A, Hill R, Wood D, Samuneva B, Dimitrova-Lukacs M. Apatite-mullite glass-ceramics; influence of fluorine content. Journal of American Ceramic Society. 2000;83:2833–2838
  12. Hill R, Stamboulis A, Law RV. The Influence of strontium substitution in fluorapatite glasses and glass-ceramics. Journal of Non Crystallised Solids. 2004;336:223–229
  13. Engelhardt G, Noftz M, Forkel K, Wishmann FG, Magi M, Samson A, et al. Structural studies of calcium aluminosilicate glasses by high resolution solid state 29Si and 27Al magic angle spinning nuclear magnetic resonance. Physics Chemistry of Glasses. 1985;26:157–165
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  15. Jana C, Braun M. 19F NMR spectroscopy of glass ceramics containing Fluorapatites. Biomaterials. 1996;17:2065–2066
  16. Lowenstein W. The distribution of aluminium in the tetrahedra of silicates and aluminates. American Minerals. 1954;39:92–94
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PII: S0300-5712(06)00032-7

doi: 10.1016/j.jdent.2005.08.005

Journal of Dentistry
Volume 34, Issue 8 , Pages 525-532 , September 2006